Discrete, continuous, normal, and binomial distributions, expected value in decision making, hypothesis testing and design of experiments (t-test, ANOVA, outlier testing), measures of central tendency and dispersion with confidence intervals, regression and curve fitting, and statistical process-control limits.
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A. Probability distributions
Distributions, Confidence Intervals and Control Limits
Discrete and continuous distributions, the binomial and normal, mean/median/mode and spread, the confidence interval for a mean, and X-bar/R control limits.
Probability and statistics is worth four to six FE-Chemical questions, and almost every one reduces to a small number of moves: name the distribution, compute a center and a spread, and convert a tolerance into a probability or a probability into a limit. The handbook hands you the formulas and the unit-normal table, so the lost points are never algebra — they are basis errors (population versus sample, a count versus a fraction) and table-reading errors (area to the left versus the right of z). This concept builds the fluency the NCEES FE Reference Handbook section 'Engineering Probability and Statistics' assumes you already have when it simply prints f(x) and a z-transform with no worked example.
Discrete versus continuous random variables
A random variable maps each outcome to a number. If it can take only separated values — number of off-spec batches, particle counts, defects per reel — it is discrete and carries a probability mass function f(xk)=P(X=xk) that sums to one. If it varies continuously — a concentration, a fill weight, a temperature — it carries a probability density function f(x), and probability is the area under the curve: P(a≤X≤b)=∫abf(x)dx. The single most common slip is asking for P(X=x) of a continuous variable; that area is zero, so continuous questions are always about intervals.
P(a≤X≤b)=∫abf(x)dx,k∑f(xk)=1
Center and spread: mean, median, mode, variance
Three measures of center answer different questions. The mean Xˉ=n1∑xi is the balance point and the one the algebra runs on; the median is the middle value once the data are ordered (the average of the two middle values when n is even), and it resists outliers; the mode is the most frequent value, and for the symmetric normal all three coincide. Spread is the variance and its square root, the standard deviation. Watch the denominator: a full population divides the squared deviations by N, but a sample divides by n−1 to stay unbiased — the FE exam tests this distinction directly.
s2=n−11i=1∑n(Xi−Xˉ)2,s=s2
The binomial distribution
When a fixed number n of independent trials each succeed with the same probability p, the count of successes is binomial. This is the natural model for sampling inspection: how many of n pulled units are defective, given a defect rate p. The mass function multiplies the number of arrangements C(n,x) by the probability of any one such arrangement pxqn−x, with q=1−p. Its mean is np and its variance is npq — note the variance is a count, not a fraction.
P(x)=C(n,x)pxqn−x,μ=np,σ2=npq
The normal distribution and the z-transform
The normal (Gaussian) is the default model for measurement scatter, and by the Central Limit Theorem the mean of a sample tends toward it regardless of the parent shape. You never integrate its bell curve by hand; instead you standardize, sliding and scaling any normal variable to the unit normal with z=(x−μ)/σ, then read the tabulated areas F(z), R(z)=1−F(z), and W(z). The discipline that prevents errors is sketching the curve, shading the area you want, and matching that shaded region to the correct column of the table.
z=σx−μ,f(x)=σ2π1e−21(σx−μ)2
Confidence interval for the mean
A confidence interval brackets the unknown population mean from a single sample. The center is always Xˉ; the half-width is a multiplier times the standard error of the mean, σ/n. Which multiplier you use depends on what you know: if the population σ is known you use the normal value zα/2 (1.960 for 95%), and if you must estimate the spread from the sample with s you use Student's tα/2,n−1, which is wider for small n and converges to z as n grows. The interval narrows only as n, so halving it costs four times the samples.
Xˉ±zα/2nσ(σ known),Xˉ±tα/2,n−1ns(σ unknown)
Statistical process-control limits
A control chart asks a different question than a confidence interval: not 'where is the mean?' but 'is the process still behaving as it did?' You take small subgroups of size n, plot each subgroup average on an X-bar chart and each subgroup range on an R chart, and set three-sigma limits from tabulated constants. The center lines are the grand average X and the average range Rˉ; the limits use A2, D3, D4 from the handbook table. A point outside the limits, or a nonrandom run inside them, signals an assignable cause — these limits come from the process itself, never from the engineering tolerance.
Classify first. 'How many out of n' with a fixed rate is binomial (μ=np). A continuous spec question is normal: standardize, sketch, shade, then read F, R, or W from the table — and remember P(within ±z)=2F(z)−1. For an interval, decide z versus t by whether σ is given or only s is computed, and never forget the n in the standard error. For control charts, pull A2, D3, D4 for the right n and use X and Rˉ, not the spec window. Carry units through, and quote final answers to three significant figures.
Key equations
Sample meanXˉ=n1∑i=1nXi
Arithmetic mean (balance point) of n observations; the statistic every interval and chart centers on.
Sample variance and standard deviations2=n−11∑i=1n(Xi−Xˉ)2,s=s2
Spread of a sample; divide by n−1 (use N for a full population). Units of s match the data; s2 is squared units.
Binomial mass functionP(x)=C(n,x)px(1−p)n−x
Probability of exactly x successes in n independent trials, each with success probability p. C(n,x)=n!/[x!(n−x)!].
Binomial mean and varianceμ=np,σ2=npq,q=1−p
Expected count and its variance (a count, not a fraction). Standard deviation σ=npq.
Normal probability densityf(x)=σ2π1e−21(σx−μ)2
Gaussian curve, mean μ, standard deviation σ. Never integrated by hand on the FE; standardize instead.
Standard-normal transformz=σx−μ
Converts any normal value to the unit normal so the handbook table gives F(z) (left area), R(z) (right area), W(z) (within ±z).
Within-band probabilityP(−z≤Z≤z)=W(z)=2F(z)−1
Fraction of a normal population inside μ±zσ; e.g. W(1.96)≈0.95.
Standard error of the meanσXˉ=nσ(or s/n)
Spread of the sample mean; shrinks only as n. Drives both the confidence interval and the X-bar chart width.
Confidence interval, sigma knownXˉ±zα/2nσ
Interval for μ when the population σ is known; z0.025=1.960 for 95%, 1.645 for 90%.
Interval for μ using sample s; t has n−1 degrees of freedom and is wider than z for small samples.
X-bar chart limitsUCL=X+A2Rˉ,LCL=X−A2Rˉ
Three-sigma limits on subgroup averages; X is the grand mean, Rˉ the mean range, A2 from the handbook table for subgroup size n.
R chart limits and process sigmaUCLR=D4Rˉ,LCLR=D3Rˉ,σ^=d2Rˉ
Limits on subgroup range; D3,D4,d2 from the table. σ^=Rˉ/d2 estimates the process standard deviation.
Worked examples
Binomial sampling inspection
Problem. A filling line produces off-spec bottles at a rate of p=0.08. An inspector pulls n=10 bottles at random. Find the probability that exactly two are off-spec, the probability that at most one is off-spec, and the expected number off-spec with its standard deviation.
Solution. Exactly two: P(2)=C(10,2)(0.08)2(0.92)8=45(0.0064)(0.5132)=0.148.
At most one: P(0)+P(1)=(0.92)10+10(0.08)(0.92)9=0.4344+0.3777=0.812.
Expected count: μ=np=10(0.08)=0.800 bottles; variance σ2=npq=10(0.08)(0.92)=0.736, so σ=0.736=0.858 bottles.
Sanity check: P(2)=0.148 is plausible since the mean count is below 1, so two defects is moderately unlikely but not rare. Answers: 0.148, 0.812, μ=0.800, σ=0.858.
P(2)=C(10,2)(0.08)2(0.92)8=0.148
Normal fraction outside spec
Problem. A reactor's product concentration is normally distributed with μ=250g/L and σ=4g/L. What fraction of product exceeds 256g/L, and what fraction falls within ±6g/L of the mean?
Solution. Standardize the upper bound: z=(256−250)/4=1.50.
Fraction above: R(1.50)=1−F(1.50)=1−0.9332=0.0668, i.e. 6.68%.
Within ±6g/L corresponds to ±z=1.50: W(1.50)=2F(1.50)−1=2(0.9332)−1=0.866, i.e. 86.6%.
Sanity check: ±1.5σ should capture most but not nearly all of a normal population, and 86.6% sits sensibly between the 68% of ±1σ and the 95% of ±2σ. Answers: 6.68% above 256, 86.6% within band.
z=4256−250=1.50,R(1.50)=0.0668
Confidence interval on conversion
Problem. Sixteen batches give a mean fractional conversion Xˉ=0.740 with sample standard deviation s=0.050. Construct a 95% confidence interval for the true mean conversion.
Solution. Population σ is unknown (only s is given), so use t with n−1=15 degrees of freedom: t0.025,15=2.131.
Standard error: s/n=0.050/16=0.0125.
Half-width: 2.131×0.0125=0.0266.
Interval: 0.740±0.0266=(0.713,0.767).
Sanity check: the interval is symmetric about 0.740 and only ±3.6% wide because n is moderate; using z=1.96 instead of t would slightly underestimate it. Answer: 95%CI=(0.713,0.767).
0.740±t0.025,15160.050=0.740±0.0266
X-bar and R control limits
Problem. A purity measurement is charted in subgroups of n=5. Over many subgroups the grand average is X=80.0% and the average range is Rˉ=4.0%. With A2=0.577, D3=0, D4=2.114, and d2=2.326, find the X-bar and R control limits and estimate the process standard deviation.
Solution. X-bar chart: UCL=80.0+0.577(4.0)=82.3%; LCL=80.0−0.577(4.0)=77.7%; center =80.0%.
R chart: UCLR=2.114(4.0)=8.46%; LCLR=0(4.0)=0; center =4.0%.
Process spread: σ^=Rˉ/d2=4.0/2.326=1.72%.
Sanity check: the X-bar limits sit about ±A2Rˉ=±2.31%, which is roughly 3σ^/n=3(1.72)/5=2.31% — consistent. Answers: X-bar (77.7,82.3)%; R (0,8.46)%; σ^=1.72%.
UCLXˉ=80.0+0.577(4.0)=82.3,LCLXˉ=77.7
Common pitfalls
•Dividing the sum of squared deviations by n for a sample: use n−1 for sample variance, N only for a full population. The FE tests this denominator directly.
•Asking for P(X=x) of a continuous variable. For the normal that probability is zero — every continuous question is about an interval, so standardize the endpoints and read areas.
•Mis-reading the unit-normal table: F(z) is the area to the LEFT, R(z)=1−F(z) to the right. Sketch and shade the region you actually want before picking a column.
•Using z=1.96 when only the sample s is known. With σ unknown the multiplier is tα/2,n−1, which is larger for small n and makes the interval correctly wider.
•Dropping the n in the standard error. The interval half-width and the X-bar limits both use σ/n, not σ — forgetting it inflates the answer by a factor of n.
•Building control limits from the engineering spec (tolerance) instead of the process data. UCL/LCL come from X, Rˉ, and the chart constants; specs belong to capability, not control.
•Confusing binomial variance with a fraction: σ2=npq is a variance in counts. The variance of the proportion p^ is pq/n, a different quantity.
References
NCEES FE Reference Handbook — Engineering Probability and Statistics
NCEES FE Reference Handbook — Statistical Quality Control (Average and Range Charts)
Montgomery & Runger, Applied Statistics and Probability for Engineers — distributions, confidence intervals, control charts
C. Hypothesis testing and design of experiments
Expected Value, Hypothesis Testing and DOE
Expected value for decisions, one- and two-sample t-tests and ANOVA, Type I/II error and significance, outlier screening, and the logic of designed experiments.
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E. Regression and curve fitting
Regression and Curve Fitting
Least-squares slope and intercept, the correlation coefficient and R-squared, residuals and the standard error of estimate, and linearizing power and exponential data.
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